Peel Hershey's Kisses chocolates then set aside.
In a mixing bowl beat together granulated sugar, brown sugar, peanut butter, egg, and butter. Add flour, baking soda, and baking powder. Mix until everything is incorporated and the dough forms.
Preheat oven to 375°. Do this in batches. Shape dough into small balls or use a cookie scoop. Roll in additional granulated sugar.
Place the cookie balls into a cookie sheet pan.
Bake in the oven for 8 to 10 minutes.
Immediately press chocolate in the middle of each cookie.
Carefully transfer the cookies into a rack to cool completely.
